chm1721 midterm

Topics: BR postcode area, Functional groups Pages: 50 (995 words) Published: October 29, 2013

 

1
 

CHM
 1321
 
 
 
 
 
 
 
 
 
 
 Second
 Midterm
 
 
 
 
 
 
 
 
 
 Apr
 1
 –
 2011
 

 
 
 

 

 
(Prof.
 S.
 Gambarotta)
 

 
 
Your
 Name:
 ___________________
 
 
 
 
 
 
 
 
 
 
 
 
 
 

 Student
 #:
 ______________
 

 
 

 
 

 
 
Exercise
  key
 
Exercise
  key
 
1
 

 
12
 

 
 
2
 

 
13
 

 
 
3
 

 
14
 

 
 
4
 

 
15
 

 
 
5
 

 
16
 

 
 
6
 

 
17
 

 
 
7
 

 
18
 

 
 
8
 

 
19
 

 
 
9
 

 
20
 

 
 
10
 

 

 

 
 
11
 

 

 

 
 

 
 

 

 

 

 

1.
 
 
 
 
 Deliver
 only
 the
 solution
 key
 in
 the
 above
 table.
 You
 can
 keep
 the
 text.
 The
 
solution
 key
 will
 be
 posted
 today
 on
 the
 web.
 

 
 
2.
 
 
 
 
 You
 must
 respond
 to
 all
 exercises.
 
 Blank
 pages
 are
 at
 the
 end.
 

 
3.
 
  open
 book
 exam
 (only
 a
 clean
 textbook
 of]=r
 printout
 of
 the
 E-­‐text
 allowed
 

 
4.
  molecular
 models
 are
 allowed
 


 

 

 

2
 

 
 1.
 

Name
 the
 following
 compound:
 
Br

 

 
A)
  (S,Z)-­‐3-­‐bromo-­‐4-­‐methylhex-­‐2-­‐ene  
B)
  (S)-­‐3-­‐bromo-­‐4-­‐methylhex-­‐2-­‐ene  
C)
  (S,Z)-­‐4-­‐bromo-­‐3-­‐methylhex-­‐4-­‐ene  
D)
  (S,E)-­‐3-­‐bromo-­‐4-­‐methylhex-­‐2-­‐ene  
E)
  (R,E)-­‐3-­‐bromo-­‐4-­‐methylhex-­‐2-­‐ene  
Ans:
  A
 

 

 

 

 

 

 

 
2.
 

What
 is
 the
 major
 product
 for
 the
 following
 reaction?
 
t-BuOH, t-BuOK

 

 

Cl

A)
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